Main Article Content

Abstract

Synthesis of SnO2 has been carried out by using extract of Cnidoscolus aconitifolius leaf as a natural capping agent. The synthesis aims to determine the effect of the use of a capping agent on the crystallinity and the size of crystals. The mass variations of the capping agent used were 5, 10, and 15 gram using the hydrothermal method at relatively low temperature (95-100°C). The synthesized of SnO2 were characterized using FTIR (Fourier Transform Infra Red Spectroscopy) and XRD (X-Ray Difraction). The results of FTIR characterization show the stretching vibration absorption band of Sn-O-Sn in the spectrum with and without capping agent at wave number 599 cm-1 and 599.333 cm-1 . XRD diffractogram shows that SnO2 without a capping agent and using a capping agent has relatively the same crystallinity. Mass variations of 5, 10, and 15 gram resulted in crystals measuring 14.37 nm, 13.75 nm, and 11.78 nm and SnO2 without capping agent measuring 15.93 nm. The results showed that the Cnidoscolus aconitifolius leaf solution could be used as a natural capping agent to produce SnO2. The results of SEM characterization show that aggregate reduction can be seen in the addition of Japanese papaya (Cnodoscolus aconitifolius) capping agent.

Keywords

aconitifolius leaf Capping agent Cnidoscolus Hidrothermal SnO2

Article Details

How to Cite
Amanta, R. C. ., Nadia Refa Fheronica, Asdim, Banon, C., Irfan Gustian, & Eka Angasa. (2023). SYNTHESIS AND CHARACTERIZATION OF SnO2 USING JAPANESE PAPAYA LEAF EXTRACT (Cnidoscolus aconitifolius) AS CAPPING AGENT BY HYDROTHERMAL METHOD. SPIN JURNAL KIMIA & PENDIDIKAN KIMIA, 5(2), 209–219. https://doi.org/10.20414/spin.v5i2.7859

References

  1. Adiwibowo, M. T., Herayati, H., Erlangga, K. & Fitria, D. A., (2020). Pengaruh Metode Dan Waktu Ekstraksi Terhadap Kualitas Dan Kuantitas Saponin Dalam Ekstrak Buah, Daun, Dan Tangkai Daun Belimbing Wuluh (Avverhoa Bilimbi L.) Untuk Aplikasi Detergen. Jurnal Integrasi Proses, 9(2), 44-50. http://dx.doi.org/10.36055/jip.v9i2.9262
  2. Begum, S., & Ahmaruzzaman, M. (2018). Biogenic synthesis of SnO2 /activated carbon nanocomposite and its application as photocatalyst in the degradation of naproxen. Applied Surface Science. 449, 280-789. https://doi.org/10.1016/j.apsusc.2018.02.069
  3. Bhosale, R., Giri, J., Pandey, B. K., Giehl, R. F. H., Hartman. A., …., Swarup, R. (2018). A mechanistic framework for auxin dependent Arabidopsis root hair elongation to low external phosphate. Nature Communications, 9 (1). 1-9. https://doi.org/10.1038/s41467-018-03851-3
  4. Chiu, H. C. dan Yeh, C. S., 2007. Hydrothermal Synthesis of SnO2 Nanoparticles and Their Gas-Sensing of Alcohol. The Journal of Physical Chemistry C, 111(20), 7256-7259. https://doi.org/10.1021/jp0688355
  5. Davar, F., Masoud, S., and Zienab, F. (2010). Synthesis and characterization of SnO2 nanoparticles by thermal decomposition of new inorganic precursor, 496(1-2), 638–643. https://doi.org/10.1016/j.jallcom.2010.02.152
  6. Fabiyi, O. A. (2021). Sustainable management of Meloidogyne incognita infecting carrot (Daucus carota): Green synthesis of silver nanoparticles with Cnidoscolus aconitifolius. Vegetos. 34, 277-285. https://doi.org/10.1007/s42535-021-00216-y
  7. Guan, M., Zhao, X., Duan, L., Cao, M., Guo, W., Liu, J. dan Zhang, W., (2013). Controlled synthesis of SnO2 Nanostructures with Different Morphologies and The Influence on Photocatalysis Properties. Journal of Applied Physics, 114(11), 114302. https://doi.org/10.1063/1.4821140
  8. Honarmand, M., Golmohammadi, M., & Naeimi, A. (2019). Biosynthesis of tin oxide (SnO2) nanoparticles using jujube fruit for photocatalytic degradation of organic dyes. Advanced Powder Technology, 30(8), 1551-1557. https://doi.org/10.1016/j.apt.2019.04.033
  9. Inderan, V., Lim, S.Y., Ong, T.S., Bastien, S., Braidy, N. dan Lee, H.L., (2015). Synthesis and Characterisations of SnO2 Nanorods Via Low Temperature Hydrothermal Method. Superlattices and Microstructures, 88, pp.396-402. https://doi.org/10.1016/j.spmi.2015.09.031
  10. Jadhav, D. B., & Kokate, R. D. (2020). Green synthesis of SnO2 using green papaya leaves for nanoelectronics (LPG sensing) application. Material Today Procceding, 26(2), 998-1004. https://doi.org/10.1016/j.matpr.2020.01.180
  11. Junbo, W., Minge, Y., Yingmin, L., Licheng, C., Yan, Z. and Bingjun, D., (2005) . Synthesis of Fe-doped Nanosized SnO2 Powders by Chemical Co-Precipitation Method. Journal of non-crystalline solids, 351(3), 228-232. https://doi.org/10.1016/j.jnoncrysol.2004.11.008
  12. Khairunnisa H. (2015). Sintesis Nanopartikel SnO2 Menggunakan Capping Agent Alami Ekstrak Air Daging Buah Lerak (Sapindus rarak DC) Dengan Prekursor Asam. Skripsi. Universitas Bengkulu. Bengkulu.
  13. Kim, S. P., Choi, M. Y. & Choi, H. C., (2016). Photocatalytic Activity of SnO2 Nanoparticles in Methylene Blue Degradation. Materials Research Bulletin, 74(16) , 85-89. https://doi.org/10.1016/j.materresbull.2015.10.024
  14. Masjedi-Arani, M. and Salavati-Niasari, M., (2016). Effect of carbohydrate sugars as a capping agent on the size and morphology of pure Zn2SnO4 nanostructures and their optical properties. Materials Letters, 174, 71- 74. https://doi.org/10.1016/j.matlet.2016.03.084
  15. Mustari, M., Evi, J., Noor, A., Rafsanjani, R. A. & Tiandho, Y., (2019). Green- Synthesis Nanopartikel SnO2 Termediasi Ekstrak Daun Pelawan (Tristaniopsis merguensis Griff.). EduMatSains: Jurnal Pendidikan, Matematika & Sains, 4(1), 41-50.
  16. Rivai, H., (2021). Petai Cina (Leucaena Leucocephala): Penggunaan Tradisional, Fitokimia, & Aktivitas Farmakologi. Deepublish.
  17. Tammina, S. K., Mandal, B. K., & Kadiyala, N. K. (2018). Photocatalytic degradation of methylene blue dye by nonconventional synthesized SnO2 nanoparticles. Environmental Nanotechnology, Monitoring & Management, 10, 339-350. https://doi.org/10.1016/j.enmm.2018.07.006
  18. Utami, M. (2020). Green Synthesis Nanopartikel SnO2 Menggunakan Capping Agent Ekstrak Daun Jarak Pagar (Jatropha Curcas L.) & Aplikasinya Sebagai Fotokatalis Degradasi Methylene Blue. Skripsi. Universitas Bengkulu. Bengkulu
  19. Viet, P. V., Thi, C. M. & Hieu, L. V., (2016). The High Photocatalytic Activity of SnO2 Nanoparticles Synthesized by Hydrothermal Method. Journal of Nanomaterials. https://doi.org/10.1155/2016/4231046
  20. Wulandari, D. D., (2017). Analisa Kesadahan Total & Kadar Klorida Air Di Kecamatan Tanggulangin Sidoarjo. Medical Technology and Public Health Journal, 1(1),14-19. https://doi.org/10.33086/mtphj.v1i1.753